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So far most of the information in this chapter has been related to mineral oils. For almost 150 years the availability, good performance, variety, and cheapness of mineral oils have made them the first choice for most applications. They still represent over 90 percent of total lubricant use, but many other liquids are used successfully as lubricants and can provide special features which make them the best choice in particular situations. Table 20.5 shows the most important types of lubricating oil and their advantages and disadvantages as compared with mineral oils. The natural oils comprise a wide variety of compounds of vegetable or animal origin, consisting mainly of organic esters. They all have better low-friction and boundary lubrication properties than mineral oils, but lower thermal and oxidative stability. Before mineral oils became generally available, natural oils and fats were the most common lubricants, and several are still widely used because their properties make them particularly suitable for special applications, as shown in Table 20.6. The diesters were the first synthetic lubricating oils to be used in large quantities. Their higher thermal and oxidative stability made them more suitable than mineral

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Capacitor C10 is placed across T1, while zener diodes D2 and D3 are used as voltage clamps diodes at the input of the transformer Transformer T1 is used to couple the audio from the Data-Alert to the phone line, once the unit has been triggered Resistor R9 is used to couple one side of the transformer to the.

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oils for gas-turbine lubrication, and by about 1960 they were almost universally used for aircraft jet engines For the even more demanding conditions of supersonic jet engines, the more complex ester lubricants such as hindered phenols and triesters were developed Phosphate esters and chlorinated diphenyls have very low-flammability characteristics, and this has led to their wide use where critical fire-risk situations occur, such as in aviation and coal mining Their overall properties are mediocre, but are sufficiently good for use where fire resistance is particularly important Other synthetic fluids such as silicones, chlorinated silicones, fluorinated silicones, fluorinated hydrocarbon, and polyphenyl ethers are all used in relatively small quantities for their high-temperature stability, but all are inferior lubricants and very expensive compared with mineral oils Several types of water-containing fluid are used in large quantities, and these are listed in Table 207.

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They are used almost entirely to provide either fire resistance or superior cooling Mineral oils can be considered as the normal, conventional oils, and alternative types are used only when they can offer some particular advantage over mineral oils Table 208 summarizes the selection of oil type in relation to the special properties required It is difficult to give precise high-temperature limits for the use of specific oil types, because the limiting temperature depends on the required life and the amount of degradation which is acceptable Even for water-containing lubricants, the upper temperature limit may be from 50 to 85 C depending on the required life, the degree of ventilation, and the amount of water loss which is acceptable Table 209 summarizes the temperature limits for a few synthetic oils, but the limits shown should be considered only approximate.

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Serious incompatibility problems can occur with lubricating oils, especially with nonmetallic materials such as rubber seals and hoses Table 2010 lists some satisfactory and unsatisfactory materials for use with various lubricants..

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Lubricating greases are not simply very viscous oils. They consist of lubricating oils, often of quite low viscosity, which have been thickened by means of finely dispersed solids called thickeners. The effect of the thickeners is to produce a semirigid structure in which the dispersion of thickener particles is stabilized by electric charges. The liquid phase is firmly held by a combination of opposite electric charges, adsorpTABLE 20.9 Range of Temperature Limits in Degrees Celsius for Some Synthetic Oils as a Function of the Required Life

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